Easy one for me. While Goldeneye and Casino Royale both do come close, OHMSS is still my favorite by a long wide mile.
Little tougher, but I had to go with LTK and the amazing Casino Royale. Dalton is criminally underrated as Bond.
Fixed the incorrect title, and voted for On Her Majesty's Secret Service (still THE best Bond film made) and the underrated Tomorrow Never Dies. Could have put The Living Daylights in there just as easily though.
The Wise Word of the Ancient Collected Spirits of Anarchy and Disharmony have guided my compass to choose... On Her Majesty's Secret Service. (I haven't seen any of the Brosnan or Craig Bonds yet. And I do not like either Dalton film.)